Contemporarypolymerchemistry3rdeditionpdf
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Contemporary Polymer Chemistry 3rd Edition PDF: A Comprehensive and Accessible Textbook for Polymer Science Students and Professionals
Contemporary Polymer Chemistry is a textbook that covers the fundamental chemistry and applications of polymers. It was written by Harry R. Allcock, Frederick W. Lampe, and James E. Mark, who are experts in the field of polymer science. The third edition of this book was published in 2003 by Pearson/Prentice Hall, and it provides an up-to-date and thorough overview of the synthetic, kinetic, structural, and applied aspects of modern polymer chemistry as well as coverage of industrial and medical applications[^1^].
The book is divided into 16 chapters that cover topics such as polymer synthesis, polymerization mechanisms, copolymers, polymer conformations, thermodynamics of polymer solutions and blends, light scattering and other characterization techniques, polymer networks and gels, rubber elasticity, viscoelasticity, glass transition, crystalline polymers, and special topics such as biopolymers, conducting polymers, and liquid-crystalline polymers. The book also includes appendices that provide mathematical tools, physical constants, and data tables for polymer science. Each chapter contains learning objectives, key terms, examples, problems, references, and further reading suggestions.
The book is suitable for undergraduate and graduate students who are studying polymer chemistry or related disciplines such as materials science, chemical engineering, or physics. It is also a valuable reference for professionals who are involved in polymer research or development. The book assumes a basic knowledge of organic chemistry and physical chemistry, but it also integrates concepts from physics, biology, statistics, and engineering as needed. The book emphasizes the logical progression of concepts and provides step-by-step derivations for example problems as well as fully derived problems for advanced calculations.
Contemporary Polymer Chemistry 3rd Edition PDF is available online for free download from various sources. However, some of these sources may not be reliable or legal. Therefore, it is recommended to purchase the book from a reputable seller or access it through a library or an academic institution. Alternatively, one can also consult other similar textbooks on polymer chemistry such as Polymer Chemistry by Timothy P. Lodge and Paul C. Hiemenz[^2^], which was published in 2020 by CRC Press and offers a well-rounded and articulate examination of polymer properties at the molecular level.
In this article, we will review some of the main topics and concepts covered in Contemporary Polymer Chemistry 3rd Edition PDF. We will also highlight some of the features and benefits of this textbook for polymer science students and professionals.
Polymer Synthesis and Polymerization Mechanisms
Polymer synthesis is the process of creating polymers from monomers or smaller units. Polymerization is the chemical reaction that links monomers together to form polymers. There are two major types of polymerization: step-growth polymerization and chain-growth polymerization. In step-growth polymerization, monomers react with each other to form dimers, trimers, and so on until a high molecular weight polymer is obtained. In chain-growth polymerization, monomers are added one at a time to an active center or a growing chain end. The book explains the principles, methods, kinetics, and mechanisms of both types of polymerization in detail. It also introduces controlled polymerization techniques that allow precise control over the molecular weight, molecular weight distribution, architecture, and functionality of polymers.
Copolymers, Polymer Conformations, and Thermodynamics of Polymer Mixtures
Copolymers are polymers that are composed of two or more different types of monomers. The structure and properties of copolymers depend on the composition, sequence, and stereochemistry of the monomer units. The book describes various types of copolymers such as random, alternating, block, graft, and star copolymers and their synthesis and applications. It also discusses the stereoregularity and tacticity of polymers and how they affect the crystallinity and morphology of polymers.
Polymer conformations are the shapes or arrangements of polymer chains in space. The conformation of a polymer chain is influenced by factors such as chain flexibility, intermolecular forces, solvent quality, temperature, and pressure. The book explains how to use statistical mechanics and thermodynamics to describe and predict the conformational behavior of polymers in solution and in bulk. It also introduces concepts such as the radius of gyration, the Flory-Huggins theory, the theta condition, the excluded volume effect, and the scaling laws.
Thermodynamics of polymer mixtures deals with the equilibrium properties and phase behavior of mixtures containing polymers such as polymer solutions, polymer blends, and polymer alloys. The book discusses how to apply thermodynamic principles and models to understand and predict the solubility, miscibility, phase separation, phase diagrams, and phase transitions of polymer mixtures. It also covers topics such as osmotic pressure, chemical potential, activity coefficient, regular solution theory, Flory-Huggins theory, lattice theory, free volume theory, and group contribution methods. aa16f39245